Ultrathin twodimensional mno 2 graphene hybrid nanostructures for highperformance, flexible planar supercapacitors. Since 2015, westfield technology group have been researching the application of graphene supercapacitors for deployment in their autonomous and human driver interface hdi evs. Ultrathin coaxial fiber supercapacitors achieving high energy and. To address this problem, we put forward a universal strategy to fabricate substratefree, ultrathin. Markondeya raj, billyde brown, himani sharma, teng sun, kyoungsik moon. Ultrathin planar graphene supercapacitors nano letters. Ultrathin wireless power module with integration of wireless. Implementation of graphene in supercapacitor electrodes.
Ultrathin mno2 sheets were welldispersed and tightly anchored on graphene sheets, which were doped with nitrogen simultaneously. Electrochemical properties of graphene oxide nanoribbons. Graphene is a thin layer of pure carbon, tightly packed and bonded together in a hexagonal honeycomb lattice. Implementation of graphene in supercapacitor electrodes 1. Microwaveanionexchange route to ultrathin cobaltnickelsulfide nanosheets for hybrid supercapacitors souleymen rafai, chen qiao, muhammad naveed, zhitao wang, waqar. The emergence of graphenelike 2d nanostructures has. This cited by count includes citations to the following articles in scholar. A perspective on twodimensional materials for planar microsupercapacitors apl materials 7, 090902 2019. The properties of graphene can be further improved by making nanocomposites with conducting polymers. Graphene is widely applied in the field of energy such as in batteries, supercapacitors, and solar cells. A new printing method produces flexible graphene micro. The hierarchical mno 2 ultrathin nanosheets uniformly decorating on graphene sheets were prepared by polyanilineassisted growth method. Facile synthesis of nitrogendoped grapheneultrathin mno2.
Nitrogendoped grapheneultrathin mno2 sheet composites ngmcs were prepared through a onestep hydrothermal method at low temperature 120 c. Therefore, graphene with highconductivity, flat morphology, good fabricability, and moderate functional groups is promising for highperformance mscs based on interdigital planar structures. Recent discoveries regarding innovative device technologies based on tfes flexible. Figure 1 illustrates the fabrication process of the microsupercapacitors on a silicon wafer. Ultrathin coaxial fiber supercapacitors achieving high. Ultrathin zns nanosheetcarbon nanotube hybrid electrode for. This technique is ideal for fabrication of ultrathin planar microsupercapacitors since it allows for the deposition of a very thin graphene patterns.
A team of researchers at the university of minnesota and northwestern university, usa, have developed a printing method to produce flexible graphene microsupercapacitors with a planar architecture suitable for integration in portable electronic devices the new process, referred to as selfaligned capillarityassisted lithography for electronics scale, begins with the creation of a. Pdf graphenebased thin film supercapacitor with graphene oxide. It is widely regarded as a wonder material because it is endowed with an abundance of astonishing traits. Sep 12, 20 twodimensional materials have been an ideal material platform for constructing flexible ultrathin film supercapacitors, offering great advantages of flexibility, ultrathinness and even transparency. Graphene based supercapacitors with improved specific capacitance and fast charging time at high current density santhakumar akannappan, karthikeyan kaliyappanb,c, rajesh kumar maniand, amaresh samuthira a,pandianb, bhao yange, yun sung lee, jaehyung jang f and wu lua,e.
This perspective article first summarizes the active materials and electrolytes used for thinfilm electrode tfebased supercapacitors. Electronic supplementary information flexible quasisolidstate planar microsupercapacitors based on cellular graphene films 1, 2, 3yuanlong shao, 2jianmin li 4yaogang li, 2hongzhi wang, 2qinghong zhang 1, 5richard b. The laser processed graphene based microplanar supercapacitor lpgmps component showed 3. Scalable fabrication of printed znmno2 planar micro. Pdf ultrathin twodimensional mno 2 graphene hybrid. Advanced solidstate asymmetric supercapacitors based on 3d graphenemno 2 and graphenepolypyrrole hybrid. Ultrathin zns nanosheetcarbon nanotube hybrid electrode. Graphene is a highly studied material due to its unique electrical, optical, and mechanical properties.
A read is counted each time someone views a publication summary such as the title, abstract, and list of authors, clicks on a figure, or views or downloads the fulltext. Laserprocessed graphene based microsupercapacitors for. Ultrathin twodimensional mno2graphene hybrid nanostructures. Ultrathin planar graphene supercapacitors university of. Combining the ultrathin structure and unique properties of graphene and 2d materials, we are of great interest in designing and creating highefficient, lowcost, environmentally friendly, advanced energy batteries, e. Using graphene and 2d materials, new designs for thinfilm planar mscs with outstanding performance have become possible, taking full advantage of their atomic layer thicknesses and flat morphology. Graphenebased inplane microsupercapacitors with high power. Polyanilineassisted growth of mno2 ultrathin nanosheets. Chenglin sun, huiming cheng and xinhe bao, arbitraryshaped graphene based planar sandwich supercapacitors on one substrate with enhanced flexibility and integration, acs nano, 10. The ones marked may be different from the article in the profile. It typically stores 10 to 100 times more energy per unit volume or mass than electrolytic capacitors, can accept and deliver charge much. Mar 27, 2017 flexible and easily reconfigurable supercapacitors show great promise for application in wearable electronics. Graphenebased inplane microsupercapacitors with high. Graphene based supercapacitors with improved specific.
Twodimensional vanadyl phosphate ultrathin nanosheets for. Pdf nearly all implantable bioelectronics are powered by bulky batteries which limit device miniaturization and lifespan. Substratefree and shapeless planar microsupercapacitors. Ultrathin twodimensional mno2 graphene hybrid nanostructures for highperformance, flexible planar supercapacitors.
Polyanilineassisted growth of mno 2 ultrathin nanosheets on graphene and porous graphene for asymmetric supercapacitor with enhanced energy. Flexible ultrathin microsupercapacitors based on laser. A perspective on twodimensional materials for planar micro. S1 was obtained by spincoating a go dispersion 2 mg ml. Flexible quasisolidstate planar microsupercapacitors. Graphene is a robust and attractive electrode material for supercapacitors because of its excellent electrical conductivity, high surfacetovolume ratio, and outstanding intrinsic doublelayer capacitance 21. Here, we report an inplane fabrication approach for ultrathin supercapacitors based on electrodes comprised of pristine graphene and multilayer reduced graphene oxide. The resulting planar supercapacitors showed a dramatic increase in capacitance compared to conventional sandwichlike supercapacitors.
Implementation of graphene in supercapacitor electrodes boris dyatkin1, majid. Micro supercapacitors based on a 3d structure with. In this work, graphene oxide nanoribbons gonrs were synthesized by unzipping. Pdf ultrathin grapheneprotein supercapacitors for miniaturized. This is a pdf file of an unedited manuscript that has been accepted for publication. The development of viable printing technologies has also provided better means for manufacturing, bringing micro supercapacitors closer to practical applications. Flexible and integrated microsupercapacitors based on. Microsupercapacitors based on laserreduced graphene with an ultrathin thickness of 20 m exhibit a very high area. Moreover, the allsolidstate supercapacitors showed an ultrahigh.
Thinfilm electrodebased supercapacitors cell press. Graphenebased supercapacitors may significantly boost the power of electric vehicles. Microwaveanionexchange route to ultrathin cobaltnickelsulfide nanosheets for hybrid supercapacitors souleymen rafai1, chen qiao1, muhammad naveed1, zhitao wang1, waqar younas1and syed. First, a thin film of graphene oxide go supplementary fig.
Jun 02, 2014 the resulting planar supercapacitors showed a dramatic increase in capacitance compared to conventional sandwichlike supercapacitors. Ultrathin planar graphene supercapacitors university of arizona. A supercapacitor sc, also called an ultracapacitor, is a highcapacity capacitor with a capacitance value much higher than other capacitors, but with lower voltage limits, that bridges the gap between electrolytic capacitors and rechargeable batteries. Ultrathin conductive graphitic carbon nitride assembly. The development of viable printing technologies has also provided better means for manufacturing, bringing microsupercapacitors closer to practical applications. A theoretical assessment, carbon on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. Here, we report an inplane fabrication approach for ultrathin supercapacitors based on.
Graphene supercapacitors store almost as much but charge in just 16 seconds. Ultrathin planar graphene supercapacitors nano letters acs. Graphene based supercapacitors with improved specific capacitance and fast charging time at high current density santhakumar akannappan, karthikeyan kaliyappanb,c, rajesh kumar maniand, amaresh samuthira a,pandianb, bhao yange, yun sung lee. The past decade has witnessed explosive developments of 2d materials and outstanding achievements of planar mscs. Microsupercapacitors mscs are important onchip micropower sources for miniaturized integrated electronics. Ngmcs electrode exhibited enhanced capacitive performances relative to those of undoped grapheneultrathin mno2. Materials chemistry a case school of engineering case western. This technique is ideal for fabrication of ultrathin planar micro supercapacitors since it allows for the deposition of a very thin graphene patterns. With the advent of atomically thin and flat layers of conducting materials such as graphene, new designs for thin film energy storage devices with good performance have become possible. Ultrathin wireless power module with integration of. Ultrathin twodimensional mno2graphene hybrid nanostructures for highperformance, flexible planar supercapacitors. Ultrathin planar graphene supercapacitors american chemical.
The device architecture offers an enhanced interaction of the electrolyte with carbon layers, leading to a good utilization of the high speci. The novel ultrathin planar devices delivered a specific capacitance of. Pdf ultrathin planar graphene supercapacitors anchal. Flexible selfcharging supercapacitor based on grapheneag3d. Microwaveanionexchange route to ultrathin cobaltnickel. This study reports the preparation of ultrathin, transparent graphene. Ultrathin printable graphene supercapacitors with ac line.
Micro supercapacitors based on laserreduced graphene with an ultrathin thickness of 20 m exhibit a very high area. Ultrathin, transparent, and flexible graphene films for. Polyanilineassisted growth of mno2 ultrathin nanosheets on. Ultrathin wireless power module with integration of wireless inductive link and supercapacitors chintan buch, p. Multilayer graphene synthesized using magnetron sputtering. Photolithographic fabrication of highperformance allsolidstate graphenebased planar microsupercapacitors with different interdigital fingers.
Flexible and easily reconfigurable supercapacitors show great promise for application in wearable electronics. To address this problem, we put forward a universal strategy to fabricate substratefree, ultrathin, shapeless planar mscs with high performance tenability under serious. Twodimensional materials have been an ideal material platform for constructing flexible ultrathinfilm supercapacitors, offering great advantages. The sing thus, the thickness of a supercapacitor is only 8. Graphene performs well as a supercapacitor material because of its high theoretical speci. Flexible ultrathin allsolidstate supercapacitors springerlink. Ultrathin, transparent, and flexible graphene films for supercapacitor application aiping yu, isaac roes, aaron davies, and zhongwei chen. Micro supercapacitors based on a 3d structure with symmetric. Graphene supercapacitor westfield autonomous vehicles. To enhance the energy density of supercapacitors, an asymmetric supercapacitor was prepared by wellmatched email protected 2 nanosheets email protected 2 as cathode material and porous graphene as anode material.
Chenglin sun, huiming cheng and xinhe bao, arbitraryshaped graphenebased planar sandwich supercapacitors on one substrate with enhanced flexibility and integration, acs nano, 10. Graphene, with unique twodimensional form and numerous appealing properties, promises to remarkably increase the energy density and power density of electrochemical energy storage devices eesds, ranging from the popular lithium ion batteries and supercapacitors to nextgeneration highenergy batteries. According to the configurations and thicknesses of tfes, various electrode processing approaches with particular emphasis on the electrochemical behavior are analyzed. Outstanding performance of activated graphene based supercapacitors in ionic liquid electrolyte from. Pdf graphene for batteries, supercapacitors and beyond. Shuanghao zheng, xingyan tang, zhongshuai wu, yuanzhi tan, sen wang, chenglin sun, huiming cheng and xinhe bao, arbitraryshaped graphene based planar sandwich supercapacitors on one substrate with enhanced flexibility and integration, acs nano, 10. Read tailoring the performance of graphenebased supercapacitors using topological defects. Electric doublelayer capacitors, also known as supercapacitors or ultracapacitors. It can be fabricated in a large scale and is readily applicable for wearable and. Graphene, supercapacitor, inplane geometry, singlelayer graphene, multilayer graphene. The inplane design is straightforward to implement and exploits efficiently the surface of each graphene layer for energy storage.
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